An ionic metalloporphyrin of manganese tetrakis-(4-N-trimethylaminophenyl)porphyrin hexafluorophosphate ([MnIIITTMAPP][PF6]5, 1c), resided in the mixed ionic liquids (ILs) of [BzMIM]BF4 and [BMIM]BF4, proved to be an efficient and recyclable catalytic system for styrene (derivative) epoxidations without the involvement of the auxiliary axial ligands.