Barium containing glasses are one of the most interesting materials due to their characteristic structural, optical, and electrical properties. These glasses can be used for sulfate bearing high level radioactive liquid waste [1], barrier of plasma display ribs [2], gamma ray shielding materials [3] and [4], and crown optical glasses [5] and [6]. Borate glasses are one of the common famous families of glass-forming materials. The ability of boron atoms to present in both trigonal and tetrahedral coordination’s with oxygen make the creation of anionic sites that accommodate the modified metal cations [7] beside forming variable borate units (such as diborate, triborate, pentaborate, and pyroborate)