P.V.K. acknowledges the support by the Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences of the U. S. Department of Energy through award DEFC02- 04ER15533. J.G.R. acknowledges the Bayer Environmental Research Fellowship administered through the Center for Environmental Science and Technology (CEST) at the University of Notre Dame and the instrumentation support in CEST. A.K. acknowledges the support of University of Notre Dame under ND Nano undergraduate fellowship program. J.Z. acknowledges the support of University of Notre Dame under iSURE undergraduate fellowship program. The authors also
acknowledge partial support of this research by the NSF-funded University of Wisconsin Materials Research Science and Engineering Center (DMR-1121288). This is contribution number NDRL 5021 from the Notre Dame Radiation Laboratory.