The density increased whereas the molar volume decreases, because varies sodium oxide concentration are 10 to30 mol%. The optical absorption spectra of glasses were measured in the wavelength range of 200-2,500 nm. The intensity of all absorption bands increased with increasing Na2O. In addition, the luminescence properties of Eu3+ dope zinc lithium sodium borate glasses system were carried out using wavelength of 394 nm, the luminescence peaks around 578,590,613 and 699 nm were observed.