The Ulsan metropolitan city in Korea includes two national industrial complexes [Ulsan Petrochemical Industrial Complex (UPIC) and On–San Industrial Complex (OSIC)] that produce various industrial products. Air pollution from these industrial complexes may pose potential health risks to nearby residential areas. Therefore, WRF–CALPUFF (Weather Research and Forecasting–California PUFF) modeling systems were used to simulate concentration distributions of typical air pollutants (PM10 and SO2), and statistics are computed to determine the models' ability to simulate observations.