Enhancement of light harvesting has been a persistent objective for elevating dye excitation and therefore power conversion efficiency of dye-sensitized solar cells (DSSCs). Here we launch a strategy of markedly enhancing light harvesting by caging TiO2 nanoparticles with curved silica microsheets. The results show that the strategy is versatile in suppressing the recombination reaction of electrons with I3− species in liquid electrolyte. Due to the superior reflective behaviors of curved silica microsheets, an optimal efficiency of 9.22% is recorded under simulated air mass 1.5 global sunlight on the DSSC in comparison with 6.51% and 7.51% from pristine TiO2 and planar silicate microsheet incorporated TiO2 photoanode based solar cells, respectively. This strategy is also believed to be applicable to other solar cells such as perovskite solar cells and quantum dot-sensitized solar cells.