Theriestilnloconsensuasboutthperocessensecessarytodisruptthe hydrogenbondsystemocfellulosetoinitiatesolvationotfhecellulosechains. SomeverybasicideasondifferentpossiblemechanismshavebeenpublishedI.n 1980Turbak(7)dividedcellulosesolventsintofourmaincategoriesbasedonthe possibleinteractionsofcellulosewithsolvents:
Cel-luloseisactingasabase,thesolventisanacid,e.gH. acid,
Cel-luloseisactingasanacidt,hesolventisabasee,.gK.OHT, riton, Cel-luloseisaligand,thesolventisacomplexingagent,e.gC.uam,Cadoxen, Cel-lulosieraseactivceompoundict,sonvertedtsoaolublteransient
derivativeorntermediatee,.gx.anthatet,ri uoroacetate.
2SO4,tri uoroacetic
Philipmpodi etdhsisystemancdategorizecdelluloseolvenitnsto
derivatizingn, on-derivatizinga, queousandnon-aqueousolvents(8)M. oreover, thisclassi cationwascombinedwiththenumbeor cfomponentsinthesolvent system(A9)l.ternativelys,olventcsabngeroupeidntcoertaimnodeosf interactionwithcelluloseaccordingtothemorphologicalchangesofthepolymer determinedbymicroscopy(10).
Theriestilnloconsensuasboutthperocessensecessarytodisruptthe hydrogenbondsystemocfellulosetoinitiatesolvationotfhecellulosechains SomeverybasicideasondifferentpossiblemechanismshavebeenpublishedI.n 1980Turbak possibleinteractionsofcellulosewithsolvents dividedcellulosesolventsintofourmaincategoriesbasedonthe (7):Cel-luloseisactingasabase, thesolventisanacid, e.gH กรดCel-luloseisactingasanacidt, hesolventisabasee, .gK.OHT riton, Cel luloseisaligand,thesolventisacomplexingagent,e.gC.uam,Cadoxen, Cel-lulosieraseactivceompoundict, sonvertedtsoaolublteransientderivativeorntermediatee, .gx.anthatet รี uoroacetate2SO4 ไตร uoroaceticPhilipmpodi etdhsisystemancdategorizecdelluloseolvenitnstoderivatizingn บน derivatizinga, queousandnon-aqueousolvents (8) ม. oreover, thisclassi cationwascombinedwiththenumbeor cfomponentsinthesolvent ระบบ (A9) l.ternativelys,olventcsabngeroupeidntcoertaimnodeosf interactionwithcelluloseaccordingtothemorphologicalchangesofthepolymer determinedbymicroscopy(10)
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hydrogenbondsystemocfellulosetoinitiatesolvationotfhecellulosechains Theriestilnloconsensuasboutthperocessensecessarytodisruptthe SomeverybasicideasondifferentpossiblemechanismshavebeenpublishedI.n 1980Turbak (7) dividedcellulosesolventsintofourmaincategoriesbasedonthe possibleinteractionsofcellulosewithsolvents:
Cel-luloseisactingasabase, thesolventisanacid, e.gH กรด
Cel-luloseisactingasanacidt, hesolventisabasee, .gK.OHT, Riton, Cel-luloseisaligand, thesolventisacomplexingagent, e.gC.uam, Cadoxen,
uoroacetate.
2SO4 ไตร uoroacetic
Philipmpodi etdhsisystemancdategorizecdelluloseolvenitnsto
derivatizingn บน derivatizinga, queousandnon-aqueousolvents (8) M oreover, thisclassi ระบบ cationwascombinedwiththenumbeor cfomponentsinthesolvent (A9) l.ternativelys, olventcsabngeroupeidntcoertaimnodeosf interactionwithcelluloseaccordingtothemorphologicalchangesofthepolymer determinedbymicroscopy (10)
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