Thermal conductivity data are important for food process modelling and design. Where reliable thermal conductivity data are not available, they need to be predicted. The most accurate ‘first approximation’ methodology for predicting the isotropic thermal conductivity of foods based only on data for composition, initial freezing temperature and temperature dependent thermal conductivity of the major food components was sought. A key feature of the methodology was that no experimental measurements were to be required. A multi-step prediction procedure employing the Parallel, Levy and Effective Medium Theory models sequentially for the components other than ice and air, ice and then air respectively is recommended. It was found to provide the most accurate predictions over the range of foods considered