The study was to determine the optimum conditions of pressurized liquid extraction (PLE) method to extract PFOS and PFOA from textiles. The study found that the optimum conditions of PLE was 100% flush volume with one extraction cycle under pressure of 1500 psi, temperature of 80 oC, and 30 minutes static extraction time. Overall average recovery percentage fortified with PFOS and PFOA at three different levels (10, 70, and 200 ng/g) were 92.4% for PFOS and 93.1% for PFOA.