Where v0,∆H* ,and β are empirical constants determined from log v versus KI type of plots. This formalism accounts, at least qualitatively, for the principal external variables since
1. It predicts a strong dependence of v on KI consistent with the behavior in region1
2. It also predicts an exponential temperature effect, as observed (Fig.12.10c). Note that for constant temperatures this result and Eq. (12.23) are of the same form.
3. Although not explicitly included in Eq.(12.28), the effect of moisture is ambedded in the preexponential factor. This come about by recognizing that the rate of reaction [Eq.(12.26)] is proportional to the concentration of water (see Prob.12.5b)
Where v0,∆H* ,and β are empirical constants determined from log v versus KI type of plots. This formalism accounts, at least qualitatively, for the principal external variables since
1. It predicts a strong dependence of v on KI consistent with the behavior in region1
2. It also predicts an exponential temperature effect, as observed (Fig.12.10c). Note that for constant temperatures this result and Eq. (12.23) are of the same form.
3. Although not explicitly included in Eq.(12.28), the effect of moisture is ambedded in the preexponential factor. This come about by recognizing that the rate of reaction [Eq.(12.26)] is proportional to the concentration of water (see Prob.12.5b)
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