As dosage of NaOHwas 0.72 g/L, pH value ofwastewater reached about 5.5, then oxidation rate of Fe2þ accelerated with increase dosage of NaOH, generating sediment as Fe(OH)3. Therefore, the removal rate of Fe2þ was higher with dosage of NaOH over 0.72 g/L and Fe2þ almost changed to iron sludge, remaining little Fe2þ in wastewater.