Although the sulfur curve shows shifts between net sulfur oxidation and net sulfur reduction in the geologic past, the magnitude of the current human impact is probably unprecedented in the geologic record. Human activities greatly increase the flux of sulfur to the atmosphere, some of which is transported globally. Humans are mining coal and extracting petroleum from the Earth's crust at a rate that mobilizes 150 x 1012 gS/yr, which is more than double the rate of 100 years ago.[16] The result of human impact on these processes is to increase the pool of oxidized sulfur (SO4) in the global cycle, at the expense of the storage of reduced sulfur in the Earth's crust. Therefore, human activities do not cause a major change in the global pools of S, but they do produce massive changes in the annual flux of S through the atmosphere.[