The study of lexical changes forms the diachronic portion of the science of onomasiology.
The ongoing influx of new words in the English language (for example) helps make it a rich field for investigation into language change, despite the difficulty of defining precisely and accurately the vocabulary available to speakers of English. Throughout its history English has not only borrowed words from other languages but has re-combined and recycled them to create new meanings, whilst losing some old words.
Dictionary-writers try to keep track of the changes in languages by recording (and, ideally, dating) the appearance in a language of new words, or of new usages for existing words. By the same token, they may tag some words as "archaic" or "obsolete".